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High Energy Batteries Work In Extreme Cold And Heat

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University of California team develops innovative electrolyte that could boost the performance of EVs in all weathers

Engineers at the University of California San Diego have developed lithium-ion batteries that perform well at freezing cold and scorching hot temperatures, while packing a lot of energy.

The researchers accomplished this feat by developing an electrolyte that is not only versatile and robust throughout a wide temperature range, but also compatible with a high energy anode and cathode.

The temperature-resilient batteries are described in a paper 'Solvent selection criteria for temperature-resilient lithium-sulphur batteries' published the week of July 4 in Proceedings of the National Academy of Sciences (PNAS).

Such batteries could allow electric vehicles in cold climates to travel farther on a single charge; they could also reduce the need for cooling systems to keep the vehicles' battery packs from overheating in hot climates, said Zheng Chen, a professor of nanoengineering at the UC San Diego Jacobs School of Engineering and senior author of the study.

“You need high temperature operation in areas where the ambient temperature can reach the triple digits and the roads get even hotter. In electric vehicles, the battery packs are typically under the floor, close to these hot roads,” explained Chen, who is also a faculty member of the UC San Diego Sustainable Power and Energy Center. “Also, batteries warm up just from having a current run through during operation. If the batteries cannot tolerate this warm-up at high temperature, their performance will quickly degrade.”

In tests, the proof-of-concept batteries retained 87.5 percent and 115.9 percent of their energy capacity at -40degC and 50degC), respectively. They also had high Coulombic efficiencies of 98.2 percent and 98.7 percent at these temperatures, respectively, which means the batteries can undergo more charge and discharge cycles before they stop working.

The batteries that Chen and colleagues developed are both cold and heat tolerant thanks to their electrolyte. It is made of a liquid solution of dibutyl ether mixed with a lithium salt. A special feature about dibutyl ether is that its molecules bind weakly to lithium ions. In other words, the electrolyte molecules can easily let go of lithium ions as the battery runs. This weak molecular interaction, the researchers had discovered in a previous study, improves battery performance at sub-zero temperatures. Plus, dibutyl ether can easily take the heat because it stays liquid at high temperatures (it has a boiling point of 141deg C).

What's also special about this electrolyte is that it is compatible with a lithium-sulphur battery, which is a type of rechargeable battery that has an anode made of lithium metal and a cathode made of sulphur. Lithium-sulphur batteries are an essential part of next-generation battery technologies because they promise higher energy densities and lower costs. They can store up to two times more energy per kilogram than today's lithium-ion batteries—this could double the range of electric vehicles without any increase in the weight of the battery pack. Also, sulphur is more abundant and less problematic to source than the cobalt used in traditional lithium-ion battery cathodes.

But there are problems with lithium-sulphur batteries. Both the cathode and anode are super reactive. sulphur cathodes are so reactive that they dissolve during battery operation. This issue gets worse at high temperatures. And lithium metal anodes are prone to forming needle-like structures called dendrites that can pierce parts of the battery, causing it to short-circuit. As a result, lithium-sulphur batteries only last up to tens of cycles.

“If you want a battery with high energy density, you typically need to use very harsh, complicated chemistry,” said Chen. “High energy means more reactions are happening, which means less stability, more degradation. Making a high-energy battery that is stable is a difficult task itself—trying to do this through a wide temperature range is even more challenging.”

The dibutyl ether electrolyte developed by the UC San Diego team prevents these issues, even at high and low temperatures. The batteries they tested had much longer cycling lives than a typical lithium-sulphur battery. “Our electrolyte helps improve both the cathode side and anode side while providing high conductivity and interfacial stability,” said Chen.

The team also engineered the sulphur cathode to be more stable by grafting it to a polymer. This prevents more sulphur from dissolving into the electrolyte. Next steps include scaling up the battery chemistry, optimising it to work at even higher temperatures and further extending cycle life.


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